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If anyone is still paying attn. to this thread, I believe this will do it. 


1. Create a folder on your hard drive for shares. i.e. c:\share
2. Create another folder in the above share. i.e. c:\share\music
2. Link the Library to this folder.
3. Delete the folder.
4. Use the mklink in an  elevated command prompt to make a symbolic link. Name the link the same as the folder you created above.
i.e - mklink /d c:\share\music \\server\music
5. Done. Now you have non-indexed UNC path as a library.


(source: https://social.technet.microsoft.com/Forums/windows/en-US/efb5b9dd-4281-4a17-947d-d55207bd6015/how-can-i-index-a-network-share)